Reversible dioxygen binding on asymmetric dinuclear rhodium centres

Takayuki Nakajima; Miyuki Sakamoto; Sachi Kurai; Bunsho Kure; Tomoaki Tanase

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Reversible dioxygen binding on asymmetric dinuclear rhodium centres

机译：不对称双核铑中心上可逆的双氧结合

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Electron-deficient dinuclear rhodium complexes [Rh_2Cl_2(μ-dpmppp)-(RNC)] (1), with the linear tetraphosphine ligand dpmppp, showed reversible binding of molecular oxygen to form asymmetric dirhodium η~2-peroxo complexes [Rh_2Cl_2(O_2)(μ-dpmppp)(RNC)] (2) stabilized by a Rh→Rh dative bond.

机译：缺电子的双核铑配合物[Rh_2Cl_2（μ-dpmppp）-（RNC）]（1）与线性四膦配体dpmppp显示分子氧可逆结合，形成不对称的铑η〜2-过氧配合物[Rh_2Cl_2（O_2）（μ-dpmppp）（RNC）]（2）通过Rh→Rh导数键稳定。

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《Chemical Communications》 |2013年第46期|5250-5252|共3页
作者
Takayuki Nakajima; Miyuki Sakamoto; Sachi Kurai; Bunsho Kure; Tomoaki Tanase;
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Department of Chemistry, Faculty of Science, Nara Women's University,Kitauoya-nishi-machi, Nara 630-8506, Japan;

Department of Chemistry, Faculty of Science, Nara Women's University,Kitauoya-nishi-machi, Nara 630-8506, Japan;

Department of Chemistry, Faculty of Science, Nara Women's University,Kitauoya-nishi-machi, Nara 630-8506, Japan;

Department of Chemistry, Faculty of Science, Nara Women's University,Kitauoya-nishi-machi, Nara 630-8506, Japan;

Department of Chemistry, Faculty of Science, Nara Women's University,Kitauoya-nishi-machi, Nara 630-8506, Japan;

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Reversible dioxygen binding on asymmetric dinuclear rhodium centres

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