Synthesis of methyl propanoate by Baeyer-Villiger monooxygenases

Hugo L. van Beek; Remko T. Winter; Graham R. Eastham; Marco W. Fraaije

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Synthesis of methyl propanoate by Baeyer-Villiger monooxygenases

机译：Baeyer-Villiger单加氧酶合成丙酸甲酯

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摘要

Methyl propanoate is an important precursor for polymethyl metha-crylates. The use of a Baeyer-Villiger monooxygenase (BVMO) to produce this compound was investigated. Several BVMOs were identified that produce the chemically non-preferred product methyl propanoate in addition to the normal product ethyl acetate.

机译：丙酸甲酯是聚甲基丙烯酸甲酯的重要前体。研究了使用Baeyer-Villiger单加氧酶（BVMO）生产该化合物。鉴定了几种BVMO，除了正常产物乙酸乙酯外，它们还产生化学上不优选的产物丙酸甲酯。

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来源
《Chemical Communications》 |2014年第86期|13034-13036|共3页
作者
Hugo L. van Beek; Remko T. Winter; Graham R. Eastham; Marco W. Fraaije;
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作者单位

Molecular Enzymology Group, Groningen Biomolecular Sciences and Biotechnology Institute, University of Groningen, Nijenborgh 4, Netherlands;

Molecular Enzymology Group, Groningen Biomolecular Sciences and Biotechnology Institute, University of Groningen, Nijenborgh 4, Netherlands;

Lucite International, Technology Centre Wilton, UK;

Molecular Enzymology Group, Groningen Biomolecular Sciences and Biotechnology Institute, University of Groningen, Nijenborgh 4, Netherlands;

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机译：新鉴定的Baeyer-Villiger单加氧酶有效合成3-乙酰氧基丙酸甲酯
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机译：通过合理设计将苯丙酮单加氧酶转化为苯环己酮单加氧酶：迈向实用的拜尔-维利格单加氧酶

Synthesis of methyl propanoate by Baeyer-Villiger monooxygenases

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