首页> 外文期刊>Chemical Communications >New members of layered oxychloride perovskites with square planar coordination: Sr_2MO_2Cl_2 (M = Mn, Ni) and Ba_2PdO_2Cl_2
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New members of layered oxychloride perovskites with square planar coordination: Sr_2MO_2Cl_2 (M = Mn, Ni) and Ba_2PdO_2Cl_2

机译:具有方形平面配位的层状氯氧化钙钛矿的新成员:Sr_2MO_2Cl_2(M = Mn,Ni)和Ba_2PdO_2Cl_2

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摘要

New members of Ruddlesden-Popper type layered oxychloride compounds, Sr_2MO_2Cl_2 (M = Mn, Ni) and Ba_2PdO_2Cl_2, were synthesized under high-pressure conditions. Synchrotron XRD analysis revealed that all the phases adopt the tetragonal space group /4/mmm, where two-dimensional sheets composed of comer-sharing MO_4/PdO_4 squares were separated by rock-salt SrCl/BaCl layers.
机译:在高压条件下合成了Ruddlesden-Popper型层状氯氧化物的新成员Sr_2MO_2Cl_2(M = Mn,Ni)和Ba_2PdO_2Cl_2。同步加速器XRD分析表明,所有相都采用四边形空间群/ 4 / mmm,其中由角共享MO_4 / PdO_4正方形组成的二维薄片被盐岩SrCl / BaCl层隔开。

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  • 来源
    《Chemical Communications》 |2014年第44期|5915-5918|共4页
  • 作者单位

    Materials Processing Unit, National Institute for Materials Science (N1MS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan;

    Superconducting Properties Unit, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044,Japan;

    Materials Analysis Station, NIMS, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan;

    Superconducting Properties Unit, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044,Japan;

    Materials Processing Unit, National Institute for Materials Science (N1MS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan;

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  • 入库时间 2022-08-17 13:15:51

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