Folded Cr_(12)Co_(12) and Cr_(12)Ni_(12) wheels: a sharp increase in nuclearity of heterometallic chromium rings

Christian Plenk; Thomas Weyhermueller; Eva Rentschler

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Folded Cr_(12)Co_(12) and Cr_(12)Ni_(12) wheels: a sharp increase in nuclearity of heterometallic chromium rings

机译：折叠的Cr_（12）Co_（12）和Cr_（12）Ni_（12）轮：异金属铬环的核数急剧增加

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摘要

Two novel record-sized heterometallic Cr_(12)M_(12) (M = Co, Ni) chromium wheels with an unusual saddle-like architecture are created by reacting appropriate precursor complexes with the bridging ligand 2,2'-bipyrimidine.

机译：通过使合适的前体络合物与桥联配体2,2'-联嘧啶反应，制得了两个具有异常鞍形结构的新型创纪录大小的杂金属Cr_（12）M_（12）（M = Co，Ni）铬轮。

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《Chemical Communications 》 |2014年第29期| 3871-3873| 共3页
作者
Christian Plenk; Thomas Weyhermueller; Eva Rentschler;
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作者单位

Institut fuer Anorganische und Analytische Chemie, Johannes Gutenberg-Universitaet Mainz, Duesbergweg 10-14, 55128 Mainz, Germany,Graduate School Materials Science in Mainz, Staudinger Weg 9, D-55128 Mainz,Germany;

Max-Planck-Institut fuer Chemische Energiekonversion, Stiftstrasse 34-36,45470 Muelheim an der Ruhr, Germany;

Institut fuer Anorganische und Analytische Chemie, Johannes Gutenberg-Universitaet Mainz, Duesbergweg 10-14, 55128 Mainz, Germany;

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Folded Cr_(12)Co_(12) and Cr_(12)Ni_(12) wheels: a sharp increase in nuclearity of heterometallic chromium rings

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