A pillared-layered zincoborate with an anionic network containing unprecedented zinc oxide chains

摘要

A semiconducting zincoborate with a pillared-layered structure, has been prepared under solvothermal conditions, showing the first example of an inorganic-organic hybrid zincoborate with an anionic network based on the interesting zinc oxide chains linked by boron atoms and B_3O_7H_2 clusters, which are further pillared by diamine molecules to form the 3-D framework.