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首页> 外文期刊>Chemical Communications >A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination
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A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination

机译：具有三齿连接的氨基-茚基配体的新型手性钇配合物，用于分子内加氢胺化

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摘要

A new chiral silicon-linked tridentate amido-indenyl ligand was developed from indene and enantiopure 1,2-cyclohexanediamine. Its yttrium complex was synthesized, characterized and applied to efficiently catalyze the intramolecular hydroamination of non-activated olefins with up to 97% ee.
机译：从茚和对映体纯的1,2-环己二胺开发了一种新的手性硅连接的三齿氨基-茚基配体。合成了其钇配合物，对其进行了表征并应用于有效催化具有高达97％ee的非活化烯烃的分子内加氢胺化反应。

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  • 来源
    《Chemical Communications》 |2014年第2期|177-179|共3页
  • 作者

    Zhuo Chai; Dezhi Hua; Kui Li; Jiang Chu; Gaosheng Yang;

  • 作者单位

    The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, Institute of Organic Chemistry, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241000, China;

    The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, Institute of Organic Chemistry, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241000, China;

    The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, Institute of Organic Chemistry, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241000, China;

    The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, Institute of Organic Chemistry, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241000, China;

    The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, Institute of Organic Chemistry, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241000, China;

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  • 入库时间 2022-08-17 13:14:52

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