STM-based molecular detection of catch-and-release of protons for bipyridine bound to phenylene杄thynylene thiol

Emiko Koyama; Takao Ishida; Hideo Tokuhisa; abdelhak Belaissaoui; Yoshinobu Nagawa; Masatoshi Kanesato

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STM-based molecular detection of catch-and-release of protons for bipyridine bound to phenylene杄thynylene thiol

机译：基于STM的联吡啶与亚苯基杄乙炔硫醇结合的质子捕获和释放的分子检测

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摘要

The protonation/deprotonation response of a novel bipyridine containing (phenylene–ethynylene) thiol adsorbed to a Au surface was investigated with scanning tunneling microscopy (STM), showing reversible changes in the average heights (～50 spots) and the height distribution arising from protonation/deprotonation.

机译：用扫描隧道显微镜（STM）研究了一种新型的联吡啶（Au表面吸附的含有（亚苯基-亚乙炔基）硫醇的联吡啶）的质子化/去质子反应，显示平均高度（〜50个斑点）的可逆变化以及质子化引起的高度分布/去质子化

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来源
《Chemical Communications》 |2004年第14期|p. 1626-1627|共2页
作者
Emiko Koyama; Takao Ishida; Hideo Tokuhisa; abdelhak Belaissaoui; Yoshinobu Nagawa; Masatoshi Kanesato;
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作者单位

Nanoarchitectonics Research Center (NARC), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 4, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562, Japan;

Institute of Mechanical Systems Engineering (IMSE), AIST, 1-2-1 Namiki, Tsukuba, Ibaraki 305-8564, Japan;

Nanoarchitectonics Research Center (NARC), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 4, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562, Japan;

Nanoarchitectonics Research Center (NARC), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 4, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562, Japan;

Nanoarchitectonics Research Center (NARC), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 4, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562, Japan;

Nanoarchitectonics Research Center (NARC), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 4, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562, Japan;

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入库时间 2022-08-17 13:33:08

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1. Protonation of Bipyridines and Their Vinylene-Phenylene-Vinylene Derivatives: Theoretical Analysis of the Positive Charge Effects [J] . Jing-Fang Pan, Zhi-Kuan Chen, Soo-Jin Chua, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第38期

机译：联吡啶及其乙烯-苯撑-亚乙烯基衍生物的质子化：正电荷效应的理论分析
2. Characterization and protonation behavior of bipyridine thiol self-assembled monolayer on Au(111) studied using X-ray photoelectron spectroscopy and scanning tunneling microscopy [J] . Hiroshi Suga, Emiko Koyama, Hideo Tokuhisa, Surface Science . 2007,第1期

机译：X射线光电子能谱和扫描隧道显微镜研究的联吡啶硫醇自组装单层在Au（111）上的表征和质子化行为
3. Protonationof Bipyridines and Their Vinylene-Phenylene-Vinylene Derivatives: Theoretical Analysis of the Positive Charge Effects [J] . Jing-Fang Pan, Zhi-Kuan Chen, Soo-Jin Chua The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第38期

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4. A Charge Density Study to Explore the Effect of Au and Pt Atoms in Thiol Substituted Oligo (Phenylene ethynylene) Molecular Nanowires [C] . C. Karthika, K. Sadasivam, R. Praveena International Conference on Advances in Basic Sciences . 2019

机译：充电密度研究探讨Au和Pt原子在硫醇取代寡核苷酸（亚苯基乙炔基）分子纳米线中的作用
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STM-based molecular detection of catch-and-release of protons for bipyridine bound to phenylene杄thynylene thiol

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