Supertetrahedral decametallic Ni(Ⅱ) clusters directed by μ_6-tris-alkoxides

Rachel Shaw; Ian S. Tidmarsh; Rebecca H. Laye; Barbara Breeze; Madeleine Helliwell; Euan K. Brechin; Sarah L. Heath; Mark Murrie; Stefan Ochsenbein; Hans-Ulrich Guedel; Eric J. L. McInnes

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Supertetrahedral decametallic Ni(Ⅱ) clusters directed by μ_6-tris-alkoxides

机译：μ_6-三醇盐指导的超四面体十金属Ni（Ⅱ）簇

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We report the syntheses, structures and magnetic properties of two decametallic Ni(Ⅱ) clusters with unprecedented super-tetrahedral cores, stabilised by the (hitherto unobserved) μ_6-coordination modes of the tris-alkoxides {MeC(CH_2O)_3}~(3-) and (C_6H_9O_3)~(3-).

机译：我们报道了两个具有前所未有的超四面体核的十金属Ni（Ⅱ）团簇的合成，结构和磁性质，这些团簇由（迄今未观察到的）三醇盐{MeC（CH_2O）_3}〜（3）的μ_6-配位模式稳定-）和（C_6H_9O_3）〜（3-）。

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《Chemical Communications》 |2004年第12期|p.1418-1419|共2页
作者
Rachel Shaw; Ian S. Tidmarsh; Rebecca H. Laye; Barbara Breeze; Madeleine Helliwell; Euan K. Brechin; Sarah L. Heath; Mark Murrie; Stefan Ochsenbein; Hans-Ulrich Guedel; Eric J. L. McInnes;
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Department of Chemistry, The University of Manchester, Manchester, UK M13 9PL;

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正文语种 eng
中图分类化学;
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入库时间 2022-08-17 13:33:09

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Supertetrahedral decametallic Ni(Ⅱ) clusters directed by μ_6-tris-alkoxides

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