Carborane functionalized pyrroles and porphyrins via the Suzuki cross-coupling reaction

Hao EH; Fronczek FR; Vicente MGH

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Carborane functionalized pyrroles and porphyrins via the Suzuki cross-coupling reaction

机译：通过Suzuki交叉偶联反应将碳硼烷官能化的吡咯和卟啉

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摘要

A new route to carboranylated pyrroles and porphyrins is reported which involves the Suzuki coupling of readily available bromo- and boronic acid-pyrroles and bromoporphyrins with functionalized carboranes; the X-ray structures of two targeted products are presented and discussed.

机译：据报道，有一种新的途径将碳硼烷化的吡咯和卟啉与功能化的碳硼烷进行铃木偶联，后者是现成的溴和硼酸吡咯和溴卟啉的偶合。介绍并讨论了两种目标产品的X射线结构。

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来源
《Chemical Communications》 |2006年第47期|p. 4900-4902|共3页
作者
Hao EH; Fronczek FR; Vicente MGH;
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作者单位

Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
NEUTRON-CAPTURE THERAPY; SUBSTITUTED PORPHYRINS; CARBORANYLPYRROLES; TOXICITY; BNCT;

机译：中子捕获疗法;取代的卟啉;香菜草;毒性;BNCT;
入库时间 2022-08-17 13:30:16

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2. The first use of porphyrins as catalysts in cross-coupling reactions:a water-soluble palladium complex with a porphyrin ligand as an efficient catalyst precursor for the Suzuki-Miyaura reaction in aqueous media under aerobic conditions [J] . Ioannis D.Kostas, Athanassios G.Coutsolelos, Georgios Charalambidis Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007,第38期

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Carborane functionalized pyrroles and porphyrins via the Suzuki cross-coupling reaction

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