Self-exchange electron transfer in high oxidation state non-oxo metal complexes: amavadin

Lenhardt J; Baruah B; Crans DC; Johnson MD

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Self-exchange electron transfer in high oxidation state non-oxo metal complexes: amavadin

机译：高氧化态非氧金属络合物中的自交换电子转移：amavadin

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The electron transfer self-exchange rate constant between the oxidized and reduced forms of amavadin equals similar to 1 x 10(5) dm(3) mol(-1) s(-1) at 25 degrees C and represents the first unambiguous example for a vanadium(IV/V) couple.

机译：氧化和还原形式的amavadin之间的电子转移自交换速率常数等于在25摄氏度下类似于1 x 10（5）dm（3）mol（-1）s（-1），代表了第一个明确的例子钒（IV / V）对。

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来源
《Chemical Communications》 |2006年第44期|p. 4641-4643|共3页
作者
Lenhardt J; Baruah B; Crans DC; Johnson MD;
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作者单位

Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA;

New Mexico State Univ, Dept Chem & Biochem, Las Cruces, NM 88003 USA;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
AQUEOUS-MEDIA; AMANITA-MUSCARIA; PERCHLORIC-ACID; ASCORBIC-ACID; VANADIUM; KINETICS; DIOXOVANADIUM(V); OXOVANADIUM(IV); NICKEL(III); CHEMISTRY;

机译：水介质;鹅膏菌;高氯酸;抗坏血酸;钒;动力学;二氧钒（V）;氧钒（IV）;镍（III）;化学;

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2. Electron transfer in non-oxovanadium(IV) and (V) complexes: Kinetic studies of an amavadin model [J] . Lenhardt JM, Baruah B, Crans DC, Pure and Applied Chemistry . 2009,第7期

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5. Protonation studies and the determination of self-exchange electron transfer rate constants using NMR spectroscopy for selected complexes of copper(II/I). [D] . Juntunen, Kerri Lynn. 1992

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Self-exchange electron transfer in high oxidation state non-oxo metal complexes: amavadin

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