Hydrophobic amplification of noncovalent organocatalysis

Kleiner CM; Schreiner PR

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Hydrophobic amplification of noncovalent organocatalysis

机译：非共价有机催化的疏水放大

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摘要

The effects of hydrogen-bonding organocatalysts and water for the acceleration of epoxide openings with a variety of nucleophiles are additive and lead to excellent yields of the catalyzed reactions in water.

机译：氢键键合有机催化剂和水对各种亲核试剂促进环氧化物开口加速的作用是加和的，并导致水中催化反应的出色收率。

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来源
《Chemical Communications》 |2006年第41期|p. 4315-4317|共3页
作者
Kleiner CM; Schreiner PR;
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作者单位

Univ Giessen, Inst Organ Chem, D-35392 Giessen, Germany;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
DIELS-ALDER REACTIONS; LEWIS-ACID CATALYSTS; HYDROGEN-BOND DONORS; ORGANIC-REACTIONS; MULTICOMPONENT REACTIONS; CLAISEN REARRANGEMENT; METAL-FREE; WATER; SOLVENT; 1; 8-BIPHENYLENEDIOL;

机译：Diels-Alder反应;路易斯酸催化剂;氢键供体;有机反应;多组分反应;Claisen重排;无金属;水;溶剂;1;8-联苯二酚;

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1. Unprecedented Hydrophobic Amplification in Noncovalent Organocatalysis "on Water": Hydrophobic Chiral Squaramide Catalyzed Michael Addition of Malonates to Nitroalkenes [J] . Bae Han Yong, Song Choong Eui ACS catalysis . 2015,第6期

机译：非共价有机核算“水”中前所未有的疏水性扩增：疏水性手性鳞甲酸催化迈克尔向Nitroallens加入丙酮酸
2. Design of Experiments: A Rational Approach Toward NonCovalent Asymmetric Organocatalysis [J] . Renzi P., Bella M. Synlett . 2017,第3期

机译：实验设计：非价位不对称有机催化的理性方法
3. Organocatalysis Intermediates as Platforms to Study Noncovalent Interactions: Integrating Fluorine Gauche Effects in Iminium Systems to Facilitate Acyclic Conformational Control [J] . Molnar Istvan Gabor, Holland Mareike C., Daniliuc Constantin, Synlett . 2016,第7期

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4. Effects of Grooved Surface with Nano-ridges on Amplification of Hydrophobic Property [C] . Dong-Ki Lee, Jun-Hyung Lee, Younghak Cho International Conference on Applied Materials and Electronics Engineering . 2013

机译：纳米脊槽表面对疏水性分组的影响
5. Organocatalysis --- Hydrazine and Sulfonimide as New Functionalities in Asymmetric Organocatalysis. [D] . He, Hao. 2010

机译：有机催化-肼和磺酰亚胺是不对称有机催化的新功能。
6. Organocatalysis Special Feature: Attractive noncovalent interactions in asymmetric catalysis: Links between enzymes and small molecule catalysts [O] . Robert R. Knowles, Eric N. Jacobsen 2010

机译：有机催化特点：不对称催化中有吸引力的非共价相互作用：酶和小分子催化剂之间的联系
7. Direct, Asymmetric Synthesis of Carbocycle‐Fused Uracils via 4+2 Cycloadditions: a Noncovalent Organocatalysis Approach [O] . Enrico Marcantonio, Claudio Curti, Lucia Battistini, 2021

机译：通过4 + 2环加入的直接，不对称合成碳纤维熔融尿嘧啶：非共价有机能分析方法
8. Hydrophobicity and Central Nervous System Agents: On the Principle of Minimal Hydrophobicity in Drug Design [R] . Hansch, C., Bjoerkroth, J. P., Leo, A. 1987

机译：疏水性与中枢神经系统药剂：药物设计中微量疏水性原理

Hydrophobic amplification of noncovalent organocatalysis

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