Enzyme stabilizer DTT catalyzes nitrilase analogue hydrolysis of nitriles

Winkler M; Glieder A; Klempier N

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Enzyme stabilizer DTT catalyzes nitrilase analogue hydrolysis of nitriles

机译：酶稳定剂DTT催化腈的腈水解酶类似水解

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摘要

Amides are the dominating products in some nitrilase catalyzed conversions of alpha-activated nitriles, but unexpectedly this hydrolytic reaction is also catalyzed by 1,4-dithio-DL-threitol ( DTT), a standard antioxidizing enzyme stabilizer.

机译：酰胺是腈激活的腈在某些腈水解酶催化转化中的主要产物，但出乎意料的是，这种水解反应也被标准的抗氧化酶稳定剂1,4-二硫代-DL-苏糖醇（DTT）催化。

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来源
《Chemical Communications》 |2006年第12期|p. 1298-1300|共3页
作者
Winkler M; Glieder A; Klempier N;
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作者单位

Graz Univ Technol, Inst Organ Chem, A-8010 Graz, Austria;

Graz Univ Technol, Inst Mol Biotechnol, A-8010 Graz, Austria;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
ARABIDOPSIS-THALIANA;

机译：阿拉伯拟南芥;

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1. Hydrolysis of Nitriles Using an Immobilized Nitrilase: Applications to the Synthesis of Methionine Hydroxy Analogue Derivatives. [J] . Rey P, Taillades J, Nore O Journal of Agricultural and Food Chemistry . 2004,第26期

机译：使用固定的腈水解酶水解腈：在蛋氨酸羟基类似物衍生物的合成中的应用。
2. Synthesis of novel N-protected beta(3)-amino nitriles: study of their hydrolysis involving a nitrilase-catalyzed step [J] . Veitia MSI, Brun PL, Jorda P, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2009,第18期

机译：新型N保护的β（3）-氨基腈的合成：涉及腈水解酶催化步骤的水解研究
3. Unexpected stereorecognition in nitrilase-catalyzed hydrolysis of beta-hydroxy nitriles [J] . Kamila S, Zhu DM, Biehl ER, Organic letters . 2006,第20期

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4. The Hydrolysis of Nitriles Catalyzed by Rhodococcus Sp.TCCC28001 Whole Cells [C] . The 12th Asian Pacific Confederation of Chemical Engineering Congress(第十二届亚太化工联盟大会暨化工展览会)论文集 . 2008

机译：红球菌TCCC28001全细胞催化的腈水解
5. Developing artificial proteases and nucleases: Catalytic hydrolysis of unactivated amides, nitriles and phosphates. Part~I. Hydrolysis of phosphate esters promoted by cobalt(III) complexes. Part~II. Hydration of nitriles catalyzed by cobalt(III) complexes. Part~III. Hydrolysis of amides promoted by cobalt(III) complexes. [D] . Kim, Jung Hee. 1992

机译：开发人造蛋白酶和核酸酶：催化水解未活化的酰胺，腈和磷酸盐。第一部分钴（III）配合物促进的磷酸酯的水解。第二部分钴（III）配合物催化的腈水合。第三部分钴（III）配合物促进的酰胺水解。
6. Laboratory‐Evolved Enzymes Provide Snapshots of the Development of Enantioconvergence in Enzyme‐Catalyzed Epoxide Hydrolysis [O] . Åsa Janfalk Carlsson, Paul Bauer, Dr. Doreen Dobritzsch, -1

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7. Erratum to: Enhancing the catalytic potential of nitrilase from Pseudomonas putida for stereoselective nitrile hydrolysis [O] . Anirban Banerjee, Praveen Kaul, U. C. Banerjee 2017

机译：错误：提高普利替玻璃的硝基酶的催化潜力进行立体选择性丁腈水解

Enzyme stabilizer DTT catalyzes nitrilase analogue hydrolysis of nitriles

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