Glycol-modified molybdate catalysts for efficient singlet oxygen generation from hydrogen peroxide

Joos Wahlen; Dirk De Vos; Walther Jary; Paul Alsters; Pierre Jacobs

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Glycol-modified molybdate catalysts for efficient singlet oxygen generation from hydrogen peroxide

机译：乙二醇改性的钼酸盐催化剂，可有效地由过氧化氢产生单线态氧

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摘要

Pretreatment of molybdate-exchanged layered double hydroxides in polyalcohols such as ethylene glycol affords heterogeneous catalysts showing largely improved oxidant efficiency compared to the unmodified materials.

机译：与多元醇相比，在多元醇（如乙二醇）中进行钼酸盐交换的层状双氢氧化物的预处理可得到均相催化剂，其氧化效率大大提高。

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来源
《Chemical Communications》 |2007年第23期|p.2333-2335|共3页
作者
Joos Wahlen; Dirk De Vos; Walther Jary; Paul Alsters; Pierre Jacobs;
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作者单位

Centre for Surface Chemistry and Catalysis, K. U. Leuven, Kasteelpark Arenberg 23 Box 2461, 3001 Leuven, Belgium;

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正文语种 eng
中图分类化学;
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入库时间 2022-08-17 13:28:21

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1. Molybdate-exchanged layered double hydroxides for the catalytic disproportionation of hydrogen peroxide into singlet oxygen: Evaluation and improvements of ~1O_2 generation by combined chemiluminescence and trapping experiments [J] . Joos Wahlen, Dirk E.De Vos, Bert F.Sels, Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2005,第0期

机译：钼酸盐交换层状双氢氧化物用于过氧化氢催化歧化成单线态氧：化学发光和捕获实验相结合评估和改善〜1O_2生成
2. Molybdate-exchanged layered double hydroxides for the catalytic disproportionation of hydrogen peroxide into singlet oxygen: Evaluation and improvements of ~1O_2 generation by combined chemiluminescence and trapping experiments [J] . Joos Wahlen, Dirk E.De Vos, Bert F.Sels, Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2005,第0期

机译：钼酸盐交换层状双氢氧化物用于过氧化氢催化歧化成单线态氧：化学发光和捕获实验相结合评估和改善〜1O_2生成
3. Lanthanum-exchanged zeolites as active and selective catalysts for the generation of singlet oxygen from hydrogen peroxide [J] . Joos Wahlen, Dirk De Vos, Sigrid De Hertogh, Chemical Communications . 2005,第7期

机译：镧交换沸石作为活性和选择性催化剂，用于由过氧化氢生成单线态氧
4. Titanium molecular sieves convert hydrogen peroxide into singlet molecular oxygen [C] . F.M. van Laar, D.E. De Vos, P. Grobet, IZC;International zeolite conference . 2001

机译：钛分子筛将过氧化氢转化为单线态分子氧
5. THE SYNTHESIS AND CHEMISTRY OF A REMOTELY FUNCTIONALIZED UNSYMMETRICALLY SUBSTITUTED 1,2-DIOXANE (PHEROMONES, TIN-HYDRIDE, PEROXIDES, SINGLET OXYGEN, HYDROGENATION). [D] . SIDENSTICK, JOHN EDWARD. 1985

机译：远程官能化的不对称取代的1,2-二恶烷（信息素，氢化锡，过氧化物，单氧，加氢）的合成与化学。
6. Efficient Hydrogen Peroxide Generation Utilizing Photocatalytic Oxygen Reduction at a Triphase Interface [O] . Zhen Liu, Xia Sheng, Dandan Wang, 2019

机译：利用三相界面上的光催化氧还原法高效产生过氧化氢
7. Vanadium Chloroperoxidase as a Catalyst for Hydrogen Peroxide Disproportionation to Singlet Oxygen in Mildly Acidic Aqueous Environment [O] . Rokus Renirie, Christel Pierlot, Jean-Marie Aubry, 2003

机译：氯化物氧化酶作为含有酸氧化物含氧的氢气过氧化物含氧水溶液中的催化剂
8. Lifetime of Singlet Oxygen in Aqueous Hydrogen Peroxide (BHP) (Baric Hydrogen Peroxide) [R] . Rodgers, M. A., Shand, M. A. 1989

机译：过氧化氢水溶液（BHp）（过氧化氢气体）中单线态氧的寿命

Glycol-modified molybdate catalysts for efficient singlet oxygen generation from hydrogen peroxide

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