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Highly Dispersed And Nano-sized Pt-based Electrocatalysts For Low-temperature Fuel Cells

机译:用于低温燃料电池的高度分散和纳米级Pt基电催化剂

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摘要

Among metals, Pt is so far the best material to be used as anode and cathode in low-temperature fuel cells. However, Pt has the drawback of being expensive and easily CO-poisoned. Thus, to produce useful electrocatalysts, significant efforts have been made worldwide on developing Pt-based catalysts with low Pt contents as well as searching for alternative materials with high catalytic activity for anodic and cathodic reactions in low-temperature fuel cells. This article presents the development of highly dispersed and nano-sized Pt-based electrocatalysts synthesized by several new methods based on our experimental results. In the case of anode materials, our proposed new method consists of the synthesis of Pt-based nano-particles in order to maximize their surface availability, combined with the use of secondary metals that promote the oxidations of methanol and CO. On the other hand, for the cathode materials, the use of the Pt catalysts mixed with metal oxides enhances their oxygen reduction reaction (ORR) activity. We anticipate that the highly dispersed Pt-based nanoparticles introduced in this article will improve the performance of anode and cathode for low-temperature fuel cells.
机译:到目前为止,在金属中,铂是在低温燃料电池中用作阳极和阴极的最佳材料。然而,Pt具有昂贵且容易被CO中毒的缺点。因此,为了生产有用的电催化剂,全世界已在开发具有低Pt含量的Pt基催化剂以及寻找具有高催化活性的替代材料以用于低温燃料电池中的阳极和阴极反应方面做出了巨大努力。本文介绍了基于我们的实验结果,通过几种新方法合成的高度分散的纳米级Pt基电催化剂的开发。对于阳极材料,我们提出的新方法包括合成Pt基纳米颗粒以使其表面利用率最大化,并结合使用可促进甲醇和CO氧化的仲金属。对于阴极材料,将Pt催化剂与金属氧化物混合使用可增强其氧还原反应(ORR)活性。我们预计,本文中介绍的高度分散的基于Pt的纳米颗粒将改善用于低温燃料电池的阳极和阴极的性能。

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