Preparation of Polycrystalline CdTe Films by Annealing of Amorphous Films Electrodeposited from Ammoniacal Alkaline Baths

摘要

A new route to prepare polycrystalline CdTe films using electrodeposition of amorphous Cd-Te films and subsequent annealing was investigated. Amorphous Cd-Te films with Te-rich compositions could be electrode-posited from ammoniacal alkaline aqueous solutions. The deposition rate of the amorphous film was much higher than that of crystalline CdTe. Annealing of the Te-rich amorphous Cd-Te film at 400 ℃ in air yielded a crystallized CdTe film with a nearly stoichiometric composition. Thermodynamic calculations of the vapor pressures of Cd and Te species suggested that the decrease in the Te content of the annealed film was due to the vaporization of Te in the forms of oxides. Although an isothermal annealing generated a number of large holes in the film, an annealing with a slow temperature ramp resulted in a crystalline CdTe film without the large holes.