An investigation into the effect of fast heating on fluidity development and coke quality for blends of coal and biomass

摘要

The addition of biomass to coking coals can reduce operational costs and carbon emissions but also reduces fluidity development. The use of heating rates up to 20 ℃ min~1 in the softening stage of coal has been investigated using high-temperature small-amplitude oscillatory-shear (SAOS) rheometry to improve the fluid characteristics of binary blends of two coking coals with Scots pine. The effects of biomass concentration and particle size, biomass torrefaction, pellet mass and thermal pre-treatment of the blend on fluidity development and semicoke strength have also been studied. Fluidity increased with an increase in heating rate and an increase in the final temperature for fast heating. Relationships were found between the minimum complex viscosity of the blend, the heating rate and the concentration of biomass, which have been used to propose an equation to calculate the heating rate necessary to achieve optimum fluidity for a particular blend with biomass. The fluid characteristics of the blend were not affected to a great extent by the particle sizes of the biomass studied (<500 μm and >500 μm) or the torrefaction of the biomass (250 ℃ for 1 h in N_2), were increased by an increase in pellet mass, and were destroyed by blend pre-heating. The semicoke strength of the blend with a mass fraction of 10% Scots pine and fast heating (10 ℃ min ~1) proved to be higher than that of the coal alone with slow heating (3 ℃ min ~1) and resulted in a 3% reduction in non-renewable carbon emissions.