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FORMATION OF INTERSTELLAR ICES BEHIND SHOCK WAVES

机译:冲击波后星际冰的形成

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摘要

We have used a coupled dynamical and chemical model to examine the chemical changes induced by the passage of an interstellar shock in well-shielded regions. Using this model, we demonstrate that the formation of H_2O in a shock will be followed in the postshock phase by depletion of the water molecules onto the grain surfaces. To attempt to discriminate between the creation of ices behind shocks and their production by means of grain surface chemistry, we examine the deuterium chemistry of water before, during, and after a shock. We show that chemical evolution in the postshock gas can account for both the deuterium fractionation and the abundance of CO_2 relative to H_2O observed in interstellar and cometary ices. Given the pervasiveness of shocks and turbulent motions within molecular clouds, the model presented here offers an alternative theory to grain surface chemistry for the creation of ices in the interstellar medium, ices that may ultimately be incorporated into comets.
机译:我们已经使用了耦合的动力学和化学模型来研究由星际冲击在屏蔽良好的区域中通过而引起的化学变化。使用该模型,我们证明在冲击后H_2O的形成将在震后阶段通过将水分子消耗到晶粒表面上来实现。为了试图区分撞击后冰的形成和通过谷物表面化学的方式产生冰,我们检查了撞击前,撞击中和撞击后水的氘化学性质。我们表明,震后气体中的化学演化可以解释氘分馏和相对于H_2O在星际和彗星冰中观察到的CO_2的丰度。考虑到分子云中冲击和湍流的普遍性,此处介绍的模型为在星际介质中形成冰提供了谷物表面化学的另一种理论,这些冰最终可能被整合到彗星中。

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