Nano- and microdot array formation by laser-induced dot transfer

摘要

Fabrication of FeSi_2 nano- and microdot array was performed by utilizing droplet ejection through laser-induced forward transfer, which we named laser-induced dot transfer (LIDT). An amorphous FeSi_2 alloy source film on a transparent support was illuminated from the support by a nanosecond excimer laser pulse patterned into migcrogrid form, resulting in size- and site-controlled dot deposition. Micro-Raman spectroscopy confirmed β-FeSi_2 semiconducting crystalline phase even on unheated substrates. Moreover, the microdots exhibited near-infrared photoluminescence at the peak wavelength of 1.57 μm, which comes from the β-FeSi_2 crystalline phase precipitated during the LIDT process. The dot size was successfully reduced to approximately 500 and 300 nm in diameter and height, respectively. This technique is useful for integrating functional nano- and microdots under atmospheric room-temperature conditions.