Formation of Cr-modified silicide coatings on a Ti-Nb-Si based ultrahigh-temperature alloy by pack cementation process

摘要

Cr-modified silicide coatings were prepared on a Ti-Nb-Si based ultrahigh temperature alloy by Si-Cr co-deposition at 1250℃, 1350℃ and 1400℃ for 5-20h respectively. It was found that both coating structure and phase constituents changed significantly with increase in the co-deposition temperature and holding time. The outer layers in all coatings prepared at 1250℃ for 5-20h consisted of (Ti,x)_5Si_3 (X represents Nb, Cr and Hf elements). (Ti,X)_5Si_4 was found as the only phase constituent in the intermediate layers in both coatings prepared at 1250℃ for 5 and 10 h, but the intermediate layers in the coatings prepared at 1250 ℃ for 15 and 20 h were mainly composed of (Ti,X)_5Si_3 phase that was derived from the decomposition of (Ti,X)_5Si_4 phase. In the coating prepared at 1350℃ for 5 h, single (Ti,X)_5Si_3 phase was found in its outmost layer, the same as that in the outer layers in the coatings prepared at 1250℃; but in the coatings prepared at 1350℃ for 10-20 h, (Nb_(1.95)Cr_(1.05))Cr_2Si_3 ternary phase was found in the outmost layers besides (Ti,X)_5Si_3 phase. In the coatings prepared at 1400℃ for 5-20h. (Nb_(1.95)Cr_(1.05))Cr_2Si_3 ternary phase was the single phase constituent in their outmost layers. The phase transformation (Ti,X)_5Si_4→(Ti,X)_5Si_3 + Si occurred in the intermediate layers of the coatings prepared at 1350 and 1400℃ with prolonging co-deposition time, similar to the situation in the coatings prepared at 1250 ℃ for 15 and 20 h, but this transformation has been speeded up by increase in the co-deposition temperature. The transitional layers were mainly composed of (Ti,X)_5Si_3 phase in all coatings. The influence of co-deposition temperature on the diffusion ability of Cr atoms was greater than that of Si atoms in the Si-Cr co-deposition processes investigated. The growth of coatings obeyed inverse logarithmic laws at all three co-deposition temperatures. The Si-Cr co-deposition coating prepared at 1350℃ for 10 h showed a good oxidation resistance due to the formation of SiO_2 and Nb, Cr-doped TiO_2 scale after oxidation at 1250℃ for 10h.