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Novel hybrid materials based on the vanadium oxide nanobelts

机译:基于氧化钒纳米带的新型杂化材料

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摘要

Novel hybrid materials based on zinc phthalocyanine and nanostructured vanadium oxides have attracted extensive attention for the development of academic research and innovative industrial applications such as flexible electronics, optical sensors and heterogeneous catalysts. Vanadium oxides nanobelts were synthesized via a hydrothermal treatment V2O5 center dot nH(2)O gel with surfactants (TBAB, CTAB) used as structure-directing agents, where CTAB - cetyltrimethylammonium bromide, TBAB - tetrabutylammonium bromide. Hybrid materials were prepared decoration of (CTA)(0.33)V2O5 flexible nanobelts with cationic zinc phthalocyanine by the ion-exchange route. Investigations of the thermal stability, morphologies and structures of the ( CTA)(0.33)V2O5, (TBA)(0.16)V2O5 nanobelts and zinc phthalocyanine exchange product were carried out. The hybrid materials based on the nanostructured vanadium oxide and zinc phthalocyanine were tested as photocatalysts for oxidation of citronellol and 2-mercaptoethanol by dioxygen. (C) 2016 Elsevier B.V. All rights reserved.
机译:基于锌酞菁和纳米结构钒氧化物的新型杂化材料已引起学术研究和创新工业应用(例如柔性电子,光学传感器和非均相催化剂)的发展的广泛关注。通过水热处理V2O5中心点nH(2)O凝胶,使用表面活性剂(TBAB,CTAB)作为结构导向剂,合成了氧化钒纳米带,其中CTAB-十六烷基三甲基溴化铵,TBAB-四丁基溴化铵。通过离子交换途径,用阳离子酞菁锌制备了(CTA)(0.33)V2O5柔性纳米带装饰杂化材料。对(CTA)(0.33)V2O5,(TBA)(0.16)V2O5纳米带和酞菁锌交换产物的热稳定性,形貌和结构进行了研究。测试了基于纳米结构的钒氧化物和酞菁锌的杂化材料作为光催化剂对香茅醇和2-巯基乙醇被双氧的氧化作用。 (C)2016 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Applied Surface Science》 |2016年第15期|395-402|共8页
  • 作者单位

    Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia|Lobachevsky State Univ, Nizhnii Novgorod 603950, Russia;

    Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia|Lobachevsky State Univ, Nizhnii Novgorod 603950, Russia;

    Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia|Lobachevsky State Univ, Nizhnii Novgorod 603950, Russia;

    Russian Acad Sci, Inst Phys Microstruct, Nizhnii Novgorod 603087, Russia;

    Russian Acad Sci, Inst Phys Microstruct, Nizhnii Novgorod 603087, Russia;

    Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia;

    Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia;

    Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia|Lobachevsky State Univ, Nizhnii Novgorod 603950, Russia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Vanadium oxides; Nanobelts; Flexible; Zinc phthalocyanine; Hydrothermal synthesis; Photocatalysis;

    机译:氧化钒;纳米带;柔性;酞菁锌;水热合成;光催化;

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