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Low-temperature (~250℃) route to lateral growth of ZnO nanowires

机译:低温(〜250℃)途径生长ZnO纳米线

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Zinc oxide nanowires were obtained through a vapor transport route at temperatures as low as around 250℃. The diameters of the nanowires are ~40 nm and their lengths reach up to a few microns. The high-resolution transmission electron microscopy showed that ZnO nanowires are of hexagonal wurtzite structures with the [1120] growth direction. Raman spectrum reveals that the ZnO nanowires are of high-quality crystal and have an oxygen deficiency. The energy dispersive x-ray spectroscopy result verifies that the nanowires contain a small amount of Bi besides Zn and O. The investigation of the growth mechanism suggests that BiI_3 plays a key role on the fabrication of ZnO nanowires around 250℃.
机译:氧化锌纳米线是通过蒸汽传输途径在低至250℃左右的温度下获得的。纳米线的直径约为40 nm,其长度可达几微米。高分辨率透射电子显微镜显示,ZnO纳米线为六方纤锌矿结构,生长方向为[1120]。拉曼光谱表明,ZnO纳米线是高质量晶体,并且缺氧。 X射线能谱分析结果表明,除了Zn和O以外,纳米线还含有少量Bi。生长机理的研究表明BiI_3在250℃左右的ZnO纳米线的制备中起着关键作用。

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