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Magnetic properties of hydrogenated Li and Co doped ZnO nanoparticles

机译:氢化锂和钴掺杂的ZnO纳米粒子的磁性

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The effect of hydrogenation on the magnetic properties of Zn_(0.85)Co_(0.05)Li_(0.10)O nanoparticles is presented. It was found that the sample hydrided at room temperature (RT) showed weak ferromagnetism, while that hydrided at 400℃ showed robust ferromagnetism at room temperature. In both cases reheating the sample at 400℃ in air converts it back into the paramagnetic state completely. The characterization of samples by x-ray and electron diffraction showed that room temperature ferromagnetism observed in the samples hydrogenated at RT is intrinsic in nature, whereas that observed in the samples hydrogenated at 400℃ is partly due to the cobalt metal clusters.
机译:提出了氢化对Zn_(0.85)Co_(0.05)Li_(0.10)O纳米粒子磁性的影响。发现在室温(RT)下氢化的样品显示出弱的铁磁性,而在400℃下氢化的样品在室温下显示出强的铁磁性。在这两种情况下,将样品在空气中重新加热到400℃都会完全转变为顺磁状态。通过X射线和电子衍射对样品进行表征表明,在室温下氢化的样品中观察到的室温铁磁性本质上是固有的,而在400℃下氢化的样品中观察到的室温铁磁部分归因于钴金属团簇。

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