Bandgap Engineering By Tuning Particle Size And Crystallinity Of Sno_2-fe_2o_3 Nanocrystalline Composite Thin Films

摘要

We report the structural and optical properties of xSnO_2- yFe_2O_3 nanocrystalline composite thin films. SnO_2 and Fe_2O_3 exhibit strong phase separation instability and their particle size and crystallinity are tunable by changing their composition and annealing temperature. The bandgap for these composites continuously increases from 2.3 to 3.89 eV. We discuss the increasing bandgap values in terms of the quantum confinement effect manifested by the decreasing size of Fe_2O_3 crystallites. The method provides a generic approach for the tuning of the bandgap in nanocomposite systems.