Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden-Popper Layered Perovskites

摘要

State-of-the-art light-emitting diodes (LEDs) are made from high-purity alloys of III-V semiconductors, but high fabrication cost has limited their widespread use for large area solid-state lighting. Here, efficient and stable LEDs processed from solution with tunable color enabled by using phase-pure 2D Ruddlesden-Popper (RP) halide perovskites with a formula (CH3(CH2)(3)NH3)(2)(CH3NH3)(n-1)PbnI3n+1 are reported. By using vertically oriented thin films that facilitate efficient charge injection and transport, efficient electroluminescence with a radiance of 35 W Sr-1 cm(-2) at 744 nm with an ultralow turn-on voltage of 1 V is obtained. Finally, operational stability tests suggest that phase purity is strongly correlated to stability. Phase-pure 2D perovskites exhibit 14 h of stable operation at peak operating conditions with no droop at current densities of several Amperes cm(-2) in comparison to mixtures of 2D/3D or 3D perovskites, which degrade within minutes.