An Ultra-Mechanosensitive Visco-Poroelastic Polymer Ion Pump for Continuous Self-Powering Kinematic Triboelectric Nanogenerators

摘要

A mechanosensitive, visco-poroelastic polymer ion pump that can rapidly establish a dense electrical double layer via mechanical pressure, thereby significantly enhancing output performance of an ionic triboelectric nanogenerator (iTENG), is described. A working mechanism of an iTENG using a highly mechanosensitive, visco-poroelastic ion pump is suggested and the optimal characteristics of the polymer ion pump are reported by investigating optical, mechanical, electrical, and electrochemical properties. Surprisingly, the pressure sensitivity of the iTENG reaches 23.3 V kPa(-1), which is tens of times the record value. To achieve controlled high-frequency pulses from an iTENG, kinematic systems using a gear train and a cam are integrated with a single grounded iTENG, which produces a maximum of 600 V and 22 mA (approximate to 2.2 W cm(-2)) at an input frequency of 1.67 Hz; after power transforming, those values are converted to 1.42 V and 225 mA. A capacitor of 1 mF can be fully charged to 2 V in only 60 s, making it possible to continuously operate a wireless-communicating self-powered humidity sensor. Also, due to the high transparency and deformability of the polymer ion pump, a self-powered transparent tactile sensor is successfully assembled using a 5 x 5 iTENG array.