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Synthesis catalytic activity and leaching studies of a heterogeneous Pd-catalyst including an immobilized bis(oxazoline) ligand

机译:含固定化双(恶唑啉)配体的多相钯催化剂的合成催化活性和浸出研究

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摘要

Graphical abstractA catalytic system including a Pd(OAc)2-bis(oxazoline) complex bonded to 3-mercaptopropyl-functionalized silica gel is presented. The catalyst was tested for Suzuki–Miyaura reactions. The heterogeneity of the catalytic system was studied indicating that there is virtually no Pd-leaching. Furthermore, the catalyst can be reused multiple times without significant loss of stability or structure.
机译:图解摘要提出了一种催化体系,该体系包括键合到3-巯基丙基官能化硅胶上的Pd(OAc)2-双(恶唑啉)配合物。测试了该催化剂的Suzuki-Miyaura反应。研究了催化体系的异质性,表明实际上没有Pd浸出。此外,催化剂可以重复使用多次,而不会显着损失稳定性或结构。<!-fig ft0-> <!-fig @ position =“ anchor” mode = f4-> <!-fig mode =“ anchred” f5-> <!-fig / graphic | fig / alternatives / graphic mode =“ anchored” m1->

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