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Recent Synthetic Studies Leading to Structural Revisions of Marine Natural Products

机译:最近的综合研究导致海洋天然产物的结构修订

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摘要

Because of the highly unique structures of marine natural products, there are many examples of structures that were originally proposed based on spectral analyses but later proven incorrect. In many cases, the total syntheses of the originally proposed structures of marine natural products has confirmed their incorrectness and the subsequent total syntheses of the newly proposed structures proved the revised structures. This review will show such cases appearing after 2005 and demonstrate how the true structures were elucidated.
机译:由于海洋天然产物的结构非常独特,因此有许多结构示例最初是根据光谱分析提出的,但后来被证明是不正确的。在许多情况下,最初提出的海洋天然产物结构的总合成已证实了它们的不正确性,随后新提出的结构的总合成又证明了修订后的结构。这次审查将显示2005年以后出现的此类案件,并说明如何阐明真实结构。

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