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Recycling the Unrecyclable with Dynamic Covalent Chemistry

机译:用动态共价化学回收不可回收物

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摘要

Materials made from organic polymers representa significant part of nearly every consumer product offered today.The advent of plastics as a commodity material has triggered majoradvances in medicine and food preservation as well as improvementof energy efficiency in cars and aircraft through weight reduction. Although plastics have in many ways revolutionizedthe way we live, they have also had a massive impact on our environment.Despite the near ubiquity of recycling bins in our homes and workplaces,much of our plastic waste ends up in landfills, or worse, dispersedin the environment, wreaking havoc in our ecosystem. Much of thissituation can be attributed to the irresponsible use and managementof plastic waste. However, many types of plastics cannot be easilyreused or recycled, even in the hands of the most conscientious consumers.In recent years, there have been considerable efforts put toward theproduction of polymers that can be made from green or renewable sourcesas well as those that can degrade into benign byproducts or even theirconstituent monomers. However, for many applications, there simplyare no suitable “green” replacement plastics. In caseswhere these materials cannot be easily recycled, the plastics areeither “downcycled”, meaning that they are reprocessedfor use in other applications as lower value materials, or simplydiscarded into landfills or other waste streams. In their latest workpublished in this issue of , Dichtel, Ellison, and co-workers show how simplechemistry can be used to give new life to previously unrecyclableplastics by harnessing the power of dynamic covalent chemistry. Theycreated a method that activates covalent cross-links in polyurethane(PU) foams to break and reform rapidly during the recycling process,allowing polymers to be melted and reshaped into new products ( ).
机译:由有机聚合物制成的材料代表在当今提供的几乎所有消费产品中,很大一部分都是。塑料作为商品材料的出现引发了重大药物和食品保藏方面的进步以及改进减轻汽车和飞机的能源效率。尽管塑料在许多方面都带来了革命性的变化在我们的生活方式上,它们也对我们的环境产生了巨大影响。尽管在我们的家庭和工作场所中普遍存在回收箱,我们的大部分塑料废料最终被填埋,或更糟的是分散了在环境中,对我们的生态系统造成了严重破坏。这很多这种情况可以归因于不负责任的使用和管理塑料废物。但是,许多类型的塑料不容易即使在最尽责的消费者手中也可以重复使用或回收。近年来,人们为由绿色或可再生资源生产的聚合物的生产以及那些可能降解为良性副产物甚至其副产物的物质组成单体。但是,对于许多应用程序来说,没有合适的“绿色”替代塑料。在案件这些材料不易回收,塑料是要么“降级”,这意味着它们已被重新处理用于其他应用中作为低价值材料,或简单地丢弃到垃圾填埋场或其他废物流中。在他们的最新作品中Dichtel,Ellison及其同事在本期杂志上发表的文章显示了多么简单化学可以用来给以前无法回收的新生活利用动态共价化学的力量制造塑料。他们创建了一种激活聚氨酯共价交联键的方法(PU)泡沫在回收过程中会迅速破裂并重新形成,使聚合物熔融并重塑成新产品()。

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