Construction of 1D/2D α-Fe2O3/SnO2 Hybrid Nanoarrays for Sub-ppm Acetone Detection

摘要

Exhaled acetone is one of the representative biomarkers for the noninvasive diagnosis of type-1 diabetes. In this work, we have applied a facile two-step chemical bath deposition method for acetone sensors based on -Fe O /SnO hybrid nanoarrays (HNAs), where one-dimensional (1D) FeOOH nanorods are in situ grown on the prefabricated 2D SnO nanosheets for on-chip construction of 1D/2D HNAs. After annealing in air, ultrafine -Fe O nanorods are homogenously distributed on the surface of SnO nanosheet arrays (NSAs). Gas sensing results show that the -Fe O /SnO HNAs exhibit a greatly enhanced response to acetone (3.25 at 0.4 ppm) at a sub-ppm level compared with those based on pure SnO NSAs (1.16 at 0.4 ppm) and pure -Fe O nanorods (1.03 at 0.4 ppm), at an operating temperature of 340°C. The enhanced acetone sensing performance may be attributed to the formation of -Fe O –SnO n-n heterostructure with 1D/2D hybrid architectures. Moreover, the -Fe O /SnO HNAs also possess good reproducibility and selectivity toward acetone vapor, suggesting its potential application in breath acetone analysis.