Manganese and Magnesium Homochiral Materials: Decoration of Honeycomb Channels with Homochiral Chains

摘要

Five homochiral open-framework materials based on manganese and magnesium camphorates exhibit homochiral connectivity from one to three dimensions, highlighting the versatility of the synthetic system reported here. Two compounds contain column of homochiral chains lining up the honeycomb channels of 3-D metal-oxygen frameworks, an unusual feature previously unobserved in inorganic-organic hybrids.