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Direct Conversion of Glycerol into Formic Acid via Water Stable Pd(II) Catalyzed Oxidative Carbon-Carbon Bond Cleavage

机译：通过水稳定的Pd（II）催化氧化氧化碳-碳键裂解将甘油直接转化为甲酸

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Using our tridentate NHC-amidate-alkoxide Pd(II) complex, we developed a catalytic method for oxidative C-C bond cleavage of glycerol. The glycerol was degraded exclusively to formic acid and CO2. Two possible degradation pathways were proposed through ¹³C labeled studies.

机译：使用我们的三齿NHC-氨基甲酸酯-醇盐Pd（II）配合物，我们开发了催化氧化甘油的C-C键的方法。甘油仅被降解为甲酸和二氧化碳。通过^{13 C标记的研究提出了两种可能的降解途径。}

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期刊名称 other
作者
Prasanna Pullanikat; Joo Ho Lee; Kyung Soo Yoo; Kyung Woon Jung;
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年(卷),期 -1(54),33
年度 -1
页码 4463–4466
总页数 15
原文格式 PDF
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关键词
NHC amidate ligand Palladium catalyst Degradation of glycerol Formic acid Oxidative catalysis;

机译：NHC酰胺化物配体;钯催化剂;甘油的降解;甲酸;氧化催化;

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专利

1. Direct conversion of glycerol into formic acid via water stable Pd(II) catalyzed oxidative carbon-carbon bond cleavage [J] . Prasanna Pullanikat, Joo Ho Lee, Kyung Soo Yoo Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2013,第33期

机译：通过水稳定的Pd（II）催化的氧化碳-碳键裂解将甘油直接转化为甲酸
2. Indium(III) chloride-catalyzed oxidative cleavage of carbon-carbon multiple bonds by tert-butyl hydroperoxide in water—a safer alternative to ozonolysis [J] . Brindaban C. Ranu, Sukalyan Bhadra, Laksmikanta Adak Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2008,第16期

机译：叔丁基过氧化氢在水中的氯化铟（III）催化的碳-碳多键的氧化裂解-一种更安全的臭氧分解方法
3. Indium(III) chloride-catalyzed oxidative cleavage of carbon-carbon multiple bonds by tert-butyl hydroperoxide in water—a safer alternative to ozonolysis [J] . Brindaban C. Ranu, Sukalyan Bhadra, Laksmikanta Adak Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2008,第16期

机译：叔丁基过氧化氢在水中的氯化铟（III）催化的碳-碳多键的氧化裂解-一种更安全的臭氧分解方法
4. Mechanistic Insights on C-C Bond Cleavage, C-O Bond Cleavage, and Hydrogen Insertion in Light Carboxylic Acids Catalyzed by Dispersed Ruthenium Clusters in Aqueous Medium [C] . Junnan Shangguan, Ya-Huei (Cathy) Chin AIChE Annual Meeting . 2015

机译：在水性介质中分散的钌簇催化的光羧酸中C-C键切割，C-O键切割和氢气插入的机械洞察
5. Base-Promoted Stoichiometric Alkyl Carbon-Halogen Bond Cleavage and Catalytic Hydrodehalogenation with Water by Rhodium Porphyrins and Iodine-Catalyzed Carbon-Carbon σ-Bond Hydrogenation with Water [D] . Yang, Wu. 2018

机译：通过铑卟啉和碘催化的碳 - 碳Σ - 致水与水的水基促进化学计量烷基卤素碳 - 卤素粘膜和催化力加氢钠
6. Stable Gold(III) Catalysts by Oxidative Addition of a Carbon-Carbon Bond [O] . Chung-Yeh Wu, Takahiro Horibe, Christian Borch Jacobsen, -1

机译：氧化碳-碳键稳定的金（III）催化剂
7. Direct conversion of glycerol into formic acid via water stable Pd(II) catalyzed oxidative carbon–carbon bond cleavage [O] . Prasanna Pullanikat, Joo Ho Lee, Kyung Soo Yoo, 2013

机译：通过水稳定Pd（II）催化氧化碳 - 碳键切割将甘油直接转化为甲酸成甲酸
8. Redox Catalysis Involving Substrate Photooxidation with Catalyst Regeneration bySubstrate Reduction. Simultaneous Oxidative C-H Bond Cleavage and Reductive C-S Bond Cleavage in Thioethers Catalyzed by W10O324- [R] . Chambers, R. C., Hill, C. L. 1990

机译：氧化还原催化与底物光氧化反应的催化剂再生通过底物还原。 W10O324催化的硫醚同时氧化C-H键断裂和还原C-s键断裂

Direct Conversion of Glycerol into Formic Acid via Water Stable Pd(II) Catalyzed Oxidative Carbon-Carbon Bond Cleavage

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