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The Redox Chemistry and Chemical Biology of H2S Hydropersulfides and Derived Species: Implications to Their Possible Biological Activity and Utility

机译:硫化氢氢过硫化物和衍生物种的氧化还原化学和化学生物学:对它们可能的生物学活性和实用性的影响

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摘要

Hydrogen sulfide (H2S) is an endogenously generated and putative signaling/effector molecule. In spite of its numerous reported functions, the chemistry by which it elicits its functions is not understood. Moreover, recent studies allude to the existence of other sulfur species besides H2S that may play critical physiological roles. Herein, the basic chemical biology of H2S as well as other related or derived species is discussed and reviewed. A particular focus of this review are the per- and poly-sulfides which are likely in equilibrium with free H2S and which may be important biological effectors themselves.
机译:硫化氢(H2S)是内源性产生的推定信号/效应分子。尽管已报道了其许多功能,但尚不清楚其引发功能的化学方法。此外,最近的研究暗示除了H2S之外还存在其他可能起关键生理作用的硫物种。在此,讨论和审查了H2S以及其他相关或衍生物种的基本化学生物学。本综述特别关注的是全硫化物和多硫化物,它们可能与游离H2S处于平衡状态,并且它们本身可能是重要的生物效应物。

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