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Occupational exposures to new dry cleaning solvents: High-flashpoint hydrocarbons and butylal

机译:职业接触新的干洗溶剂:高闪点烃和丁醛

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摘要

The dry cleaning industry is moving away from using perchloroethylene. Occupational exposures to two alternative dry cleaning solvents, butylal and high-flashpoint hydrocarbons, have not been well characterized. We evaluated four dry cleaning shops that used these alternative solvents. The shops were staffed by Korean- and Cantonese-speaking owners, and Korean-, Cantonese-, and Spanish-speaking employees. Because most workers had limited English proficiency we used language services in our evaluations. In two shops we collected personal and area air samples for butylal. We also collected air samples for formaldehyde and butanol, potential hydrolysis products of butylal. Because there are no occupational exposure limits for butylal, we assessed employee health risks using control banding tools. In the remaining two shops we collected personal and area air samples for high-flashpoint hydrocarbon solvents.In all shops the highest personal airborne exposures occurred when workers loaded and unloaded the dry cleaning machines and pressed dry cleaned fabrics. The air concentrations of formaldehyde and butanol in the butylal shops were well below occupational exposure limits. Likewise, the air concentrations of high-flashpoint hydrocarbons were also well below occupational exposure limits. However, we saw potential skin exposures to these chemicals. We provided recommendations on appropriate work practices and the selection and use of personal protective equipment. These recommendations were consistent with those derived using control banding tools for butylal. However, there is insufficient toxicological and health information to determine the safety of butylal in occupational settings. Independent evaluation of the toxicological properties of these alternative dry cleaning solvents, especially butylal, is urgently needed.
机译:干洗行业正在逐渐放弃使用全氯乙烯。在职业接触两种替代干洗溶剂中,丁醛和高闪点碳氢化合物的特征尚不明确。我们评估了使用这些替代溶剂的四家干洗店。这些商店的员工由讲韩语和广东话的业主以及讲韩语,广东话和西班牙语的员工组成。由于大多数工人的英语能力有限,因此我们在评估中使用了语言服务。在两家商店中,我们收集了个人和区域的丁醛空气样本。我们还收集了空气样本中的甲醛和丁醇(丁醛的潜在水解产物)。由于对丁醛没有职业接触限值,因此我们使用对照条带工具评估了员工的健康风险。在剩余的两家工厂中,我们收集了高闪点烃类溶剂的个人和区域空气样本。在所有工厂中,当工人装卸干洗机和压榨干洗后的织物时,个人空气暴露量最高。丁醛车间中的甲醛和丁醇的空气浓度远低于职业接触限值。同样,高闪点碳氢化合物的空气浓度也远低于职业暴露极限。但是,我们发现这些化学物质可能会导致皮肤暴露。我们提供了有关适当工作惯例以及个人防护设备的选择和使用的建议。这些建议与使用丁基胶的对照分带工具得出的建议一致。但是,没有足够的毒理学和健康信息来确定丁醛在职业环境中的安全性。迫切需要对这些替代干洗溶剂(尤其是丁醛)的毒理学性质进行独立评估。

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