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Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation

机译：钌催化的C-C键形成转移加氢使苯乙烯与伯醇或醛进行区域选择性氢羟烷基化

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摘要

>Feedstocks to Building Blocks. Transfer hydrogenative coupling of styrene with primary alcohols delivers branched or linear adducts from benzylic or aliphatic alcohols when modified by AgOTf or HBF4, respectively. Related 2-propanol mediated reductive couplings also are described.

机译：>从原料到砌块。苯乙烯与伯醇的加氢转移偶联分别由AgOTf或HBF4改性时，可从苄基或脂族醇中得到支链或直链加合物。还描述了相关的2-丙醇介导的还原偶联。

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期刊名称 other
作者
Mr. Hongde Xiao; Mr. Gang Wang; Prof. Michael J. Krische;
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作者单位

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年(卷),期 -1(55),52
年度 -1
页码 16119–16122
总页数 10
原文格式 PDF
正文语种
中图分类
关键词
Homogenous Catalysis Cross-Coupling C-C Bond Formation Ruthenium Hydrogenation;

机译：均相催化;交叉偶联;CC键形成;钌;加氢;

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专利

1. Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation [J] . Xiao Hongde, Wang Gang, Krische Michael J. Angewandte Chemie . 2016,第52期

机译：苯乙烯催化的C-C键形成转移加氢使苯乙烯与伯醇或醛进行区域选择性氢羟烷基化
2. Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level Employing 1,3-Enynes as Surrogates to Preformed Allenylmetal Reagents:A Ruthenium-Catalyzed C-C Bond-Forming Transfer Hydrogenation [J] . Ryan L.Patman, Vanessa M.Williams, John F.Bower Angewandte Chemie . 2008,第28期

机译：从1,3-炔烃作为代用品的醇或醛氧化级羰基炔丙基化反应到预先形成的烯基金属试剂：钌催化的C-C键形成转移加氢
3. Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents [J] . Fumitoshi Shibahara, John F. Bower, Michael J. Krische Journal of the American Chemical Society . 2008,第20期

机译：钌催化的C-C键形成转移加氢：采用无环1,3-二烯作为替代物的醇或醛氧化水平的羰基烯丙基化成预制的烯丙基金属试剂
4. Ru/CeO2-Catalyzed Allyl Transfer Reaction of Homoallyl Alcohols to Aldehydes via C-C Bond Cleavage [C] . Hiroki Miura, Saburo Hosokawa, Teruyuki Kondo Symposium on Organometallic Chemistry . 2008

机译：Ru / CeO 2催化通过C-C键切割将Homoall醇的烯丙基转移反应转化为醛
5. New strategies for ruthenium catalyzed C-C bond formation. [D] . Zhang, Jing. 2014

机译：钌催化C-C键形成的新策略。
6. Hydroacylation of 2-Butyne from the Alcohol or Aldehyde Oxidation Level via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation [O] . Vanessa M. Williams, Joyce C. Leung, Ryan L. Patman, -1

机译：经由钌催化的C-C键形成氢转移反应2-丁炔从醇或醛氧化水平的加氢酰化
7. Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C−C Bond Forming Transfer Hydrogenation [O] . Hongde Xiao, Gang Wang, Michael J. Krische 2016

机译：通过钌催化的C-C键形成转移氢化与伯醇或醛的苯乙烯区域选择性羟基烷基化

Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation

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