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Transformation of Solid Waste into Nanoporous Carbonvia Carbothermic Reduction

机译:固体废物转化为纳米多孔碳通过减少碳热

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摘要

Continuous population growth and rapid urbanization will outpace the global capacity of solid-waste disposal. Although pyrolysis, in the waste management sector, has been regarded as a savior to bring potential returns, it has struggled against high operation costs. Here, we found that simple pyrolysis of properly mixed wastes [e.g., organic wastes (C) + metal wastes in the form of metal oxides (MxOy)] can bring about the carbothermic reduction [C(s) + MxOy(s) → C′(s) + M(s) + CO(g)] caused by the thermodynamic reducibility of metal oxide. This process consequently produced not only nanoporous carbon powder usable for energy storage devices but also nanoporous carbon fully decorated with magnetic nanoparticles useful for magnetic applications. We believe that the carbothermic reduction process, historically used for metal refining, could be a promising alternative to resolve the long-pending issues of the conventional pyrolysis approach as well as to produce useful nanoporous carbon with ease. Our method could be a simple and effective way to transform ubiquitous solid waste into useful resourcesin the form of nanoporous carbon.
机译:人口的持续增长和快速的城市化将超过全球固体废物处理能力。尽管热解在废物管理领域一直被认为是带来潜在回报的救星,但它仍在与高昂的运营成本作斗争。在这里,我们发现适当混合的废物[例如有机废物(C)+金属氧化物形式的金属废物(MxOy)]的简单热解可以实现碳热还原[C(s)+ MxOy(s)→C ”(s)+ M(s)+ CO(g)]由金属氧化物的热力学还原性引起。因此,该方法不仅产生了可用于能量存储装置的纳米多孔碳粉末,而且还产生了用用于磁性应用的磁性纳米颗粒完全修饰的纳米多孔碳。我们认为,历史上用于金属精炼的碳热还原工艺可能是解决常规热解方法长期未解决的问题以及轻松生产有用的纳米孔碳的有前途的替代方法。我们的方法可能是将无处不在的固体废物转化为有用资源的简单有效方法以纳米孔碳的形式存在。

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