Practical high-yield synthesis of thiol-terminated diacetylenes for formation of conductive monolayers

摘要

Self-assembled monolayers of thiol terminated conjugated diacetylenes can be cross-linked using ultraviolet light to form highly conjugated polydiacetylenic conductive monolayers; however, the reported syntheses of the diacetylene monomers present numerous problems that prevent the wide spread application of these in functional materials. We report a redesigned four-step synthesis that proceeds in 75–80 % overall yields and allows gram scale production of an array of thiol terminated conjugated diacetylenes, thereby allowing examination and application of these low-dimensional conductive materials.