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Metal-Free Synthesis of Functionalized TetrasubstitutedAlkenes by Three-Component Reaction of Alkynes Iodine and SodiumSulfinates

机译：功能化四取代的无金属合成炔烃碘和钠的三组分反应生成烯烃亚硫酸盐

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摘要

An operationally simple, efficient, and metal-/peroxide-free three-component reaction of alkynes, iodine, and sodium sulfinates has been developed for the construction of highly functionalized tetrasubstituted alkenes. Iodo- and sulfonyl-containing tetrasubstituted alkenes, such as vinyl ketones, allylic alcohols, and conjugated enynes, could be obtained regio- and stereoselectively in up to 96% yield.

机译：炔烃，碘和亚磺酸钠的操作简单，有效且无金属/过氧化物的三组分反应已经开发出来，用于构建高度官能化的四取代烯烃。含碘和磺酰基的四取代烯烃，例如乙烯基酮，烯丙基醇和共轭烯炔，可以区域和立体选择性地获得，产率高达96％。

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期刊名称 ACS Omega
作者
Jitan Zhang; *; Zhenda Liang; Jun Wang; Ziyi Guo; Changqing Liu; Meihua Xie; *;
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年(卷),期 2018(3),12
年度 2018
页码 18002–18015
总页数 14
原文格式 PDF
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专利

1. Metal-Free Synthesis of Functionalized Tetrasubstituted Alkenes by Three-Component Reaction of Alkynes, Iodine, and Sodium Sulfinates [J] . Jitan Zhang, Zhenda Liang, Jun Wang, ACS Omega . 2018,第12期

机译：炔烃，碘和亚磺酸钠的三组分反应无金属合成功能化四取代的烯烃
2. Three-component reactions of isochromenylium tetrafluoroborates via non-classical [4+2]-intermediates: Mild one-step metal-free synthesis of functionalized dihydronaphthalenes and tetrahydronaphthalenes [J] . Hu Z.-L., Yang Z.-Y., Wang S., Chemistry: A European journal . 2011,第4期

机译：非经典[4 + 2]-中间体通过四氟硼酸异铬鎓的三组分反应：轻度一步合成无金属的官能化二氢萘和四氢萘
3. Three-Component Reactions of Isochromenylium Tetrafluoroborates via Non-Classical [4+2]-Intermediates: Mild One-Step Metal-Free Synthesis of Functionalized Dihydronaphthalenes and Tetrahydronaphthalenes [J] . Dr. Zhi-Long Hu, Dr. Zhen-Yu Yang, Dr. Shaozhong Wang, Chemistry - A European Journal . 2011,第4期

机译：经由非经典[4 + 2]-中间体的四氟硼酸异丙烯腈的三组分反应：轻度一步法合成的功能化二氢萘和四氢萘的无金属合成
4. The Synthesis of Mesoporous Ag/SBA-15 and Catalytic Reaction of Propargylamines via a Three-Component Coupling Reaction of Aldehyde, Alkyne and Amine [C] . Dong Tian CEAM 2012 . 2012

机译：通过醛，炔烃，炔烃和胺的三组分偶联反应合成炔孔Ag / SBA-15和丙酰胺的催化反应
5. Synthesis of functionalized organic molecules using copper catalyzed cyclopropanation, atom transfer radical reactions and sequential azide-alkyne cycloaddition [D] . Ricardo, Carolynne Lacar 2011

机译：铜催化环丙烷化，原子转移自由基反应和叠氮化物-炔烃环加成反应合成功能化有机分子
6. A Simple Approach to Bioconjugation at Diverse Levels: Metal-Free Click Reactions of Activated Alkynes with Native Groups of Biotargets without Prefunctionalization [O] . Xianglong Hu, Xueqian Zhao, Benzhao He, 2018

机译：在不同水平上生物共轭的简单方法：活化炔烃与天然目标生物组的无金属点击反应而无需预功能化
7. Metal-Free Synthesis of Functionalized Tetrasubstituted Alkenes by Three-Component Reaction of Alkynes, Iodine, and Sodium Sulfinates [O] . Jitan Zhang, Zhenda Liang, Jun Wang, 2018

机译：通过炔烃，碘和硫酸钠的三分组分反应，无金属化官能化四氢烯烃的合成

Metal-Free Synthesis of Functionalized TetrasubstitutedAlkenes by Three-Component Reaction of Alkynes Iodine and SodiumSulfinates

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