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Decontamination of ubiquitous harmful microbial lineages in water using an innovative Zn2Ti0.8Fe0.2O4 nanostructure: dielectric and terahertz properties

机译:使用创新的Zn2Ti0.8Fe0.2O4纳米结构净化水中普遍存在的有害微生物谱系:介电和太赫兹特性

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摘要

Many ubiquitous dangerous microbial lines could originate in different sources of polluted water and be distributed to tap water, which could cause multiple types of illnesses to humans and livestock. Despite enormous attempts to guarantee safety of potable water, these species are still regarded to be threated prevalent health issues and concerns. However, these species need a powerful disinfectant to be removed from contaminated water for receiving clean and healthy water. This study was therefore conducted to produce magnificent magnetic iron titanate zinc nano-particles (Zn2Ti0.8Fe0.2O4 MNPs) as a sophisticated approach for drinking water (DW) and wastewater purification. The identification of crystalline phase, dielectric and terahertz spectroscopy of iron zinc titanate nanostructure prepared via acidic sol-gel process and calcined at 800 °C. Results show that the formation of cubic structure for Zn2TiO4 phase, and the dielectric constant (εʹ) decreased with the higher frequency, tan (δ) has higher values at lower frequency and the conductivity increases relatively with frequency that attributes to the high resistive grain boundaries. Absorption coefficient, refractive index and dielectric properties of iron zinc titanate nano-particles was estimated via time domain-terahertz spectrometer and adjusted via the applied electric field. In particular, the Gram-negative bacteria were more prone than other microbes tested to the Magnetic Nano-Particles (MNPs). Results also was ascertained that the minimum inhibitory concentration (MIC) was 25 ppm at 30 min for E. coli and Salmonella enterica, 45 min for Listeria monocyteogens, Staphylococcus aureus, and Candida albicans and 60 min for Aspergillus niger with a noticeable bactericidal impact. Results exhibit that the MNPs explored are non-toxic and protected for individuals and the environment. MNPs can, therefore, be proposed as an expedient and impressive nano-scale applicant for inactivation during the drinking water and wastewater conservation of the prevailing dangerous microbes.
机译:许多普遍存在的危险微生物系可能起源于不同的污染水源,并被分配到自来水中,这可能对人类和牲畜造成多种疾病。尽管为确保饮用水安全做出了巨大努力,但这些物种仍被认为是威胁普遍健康的问题。但是,这些物种需要强大的消毒剂才能从受污染的水中去除,以接收干净健康的水。因此,进行这项研究以生产宏伟的钛酸磁性铁锌纳米颗粒(Zn2Ti0.8Fe0.2O4 MNPs),作为饮用水(DW)和废水净化的先进方法。钛酸锌铁纳米结构的结晶相的鉴定,介电和太赫兹光谱的鉴定是通过酸性溶胶凝胶法制备的,并在800°C下煅烧。结果表明,Zn2TiO4相的立方结构形成,介电常数(εʹ)随频率增加而降低,tan(δ)在较低频率下具有较高的值,电导率随频率的增加而增加,这归因于高电阻晶界。钛酸锌铁纳米颗粒的吸收系数,折射率和介电性能通过时域太赫兹光谱仪估算,并通过施加的电场进行调节。尤其是,革兰氏阴性细菌比经磁性纳米颗粒(MNPs)测试的其他微生物更易生。还确定了结果,大肠杆菌和沙门氏菌在30分钟时的最低抑菌浓度(MIC)为25 ppm,单核细胞增生李斯特菌,金黄色葡萄球菌和白色念珠菌为45分钟,黑曲霉为60分钟,具有明显的杀菌作用。结果表明,所探索的MNP对人体和环境均无毒且受保护。因此,可以将MNPs推荐为在盛行的危险微生物的饮用水和废水保护期间灭活的便捷且令人印象深刻的纳米级申请人。

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