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Aqueous solution synthesis of reduced graphene oxide-germanium nanoparticles and their electrical property testing

机译:还原型氧化石墨烯-锗纳米颗粒的水溶液合成及其电性能测试

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摘要

Aqueous solution synthesis of reduced graphene oxide-germanium nanoparticles (RGO-GeNPs) was developed using graphene oxide (GO) as stabilizer, which could be conducive to obtain better excellent electrical properties. The information about morphology and chemical composition of the nanomaterials were obtained by TEM, FTIR, EDS, and XRD measurements. Stable aqueous dispersibility of RGO-GeNPs was further improved by poly(sodium 4-styrenesulfonate) (PSS) to obtain amphiphilic polymer-coated RGO-GeNPs (PSS-RGO-GeNPs). A possible mechanism to interpret the formation of RGO-GeNPs was proposed. The as-synthesized RGO-GeNPs showed excellent battery performance when used as an anode material for Li ion batteries. The resulting nanocomposites exhibited high specific capacity and good cycling stability after 80 cycles. This study showed a facile strategy to synthetize graphene and Ge nanocomposites which can be a hopeful anode material with excellent electrical properties for lithium ion batteries.
机译:以氧化石墨烯(GO)为稳定剂,开发了还原型氧化石墨烯-锗纳米颗粒(RGO-GeNPs)的水溶液合成方法,有利于获得更好的优良电性能。通过TEM,FTIR,EDS和XRD测量获得了纳米材料的形貌和化学组成信息。聚(4-苯乙烯磺酸钠)(PSS)进一步提高了RGO-GeNPs的稳定水分散性,从而获得了两亲性聚合物包覆的RGO-GeNPs(PSS-RGO-GeNPs)。提出了一种可能的机制来解释RGO-GeNPs的形成。合成后的RGO-GeNPs用作锂离子电池的负极材料时,具有出色的电池性能。所得的纳米复合材料在80次循环后显示出高比容量和良好的循环稳定性。这项研究表明了一种简便的策略来合成石墨烯和Ge纳米复合材料,这可能是一种希望的负极材料,具有优异的锂离子电池电性能。

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