Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor

摘要

The YSZ–NiO ceramics for solid oxide fuel cells (SOFCs) anode have been investigated. A series of specimens were singly reduced in a hydrogenous atmosphere (Ar–5 vol% H2 mixture) at 600 °C under the pressure of 0.15 MPa or subjected to ‘reduction in the mixture–oxidation in air’ (redox) cycling at 600 °C. The YSZ–Ni cermets formed in both treatment conditions were then aged in ‘water vapor in Ar–5 vol% H2 mixture’ atmosphere at 600 °C under the pressure of 0.15 MPa. Additionally, the behaviour of the as-received material in this atmosphere was studied. It was revealed that small amount of water vapor in Ar–5 vol% H2 mixture (water vapor pressure below 0.03 MPa) does not affect the reduction of the nickel phase in the YSZ–NiO ceramics, but causes some changes in the YSZ–Ni cermet structure. In particular, nanopore growth in tiny Ni particles takes place. At higher concentration of water vapor in the mixture (water vapor pressure above 0.03–0.05 MPa), converse changes in the kinetics of reduction occur. The best physical and mechanical properties were revealed for the material treated by redox cycling after holding at 600 °C in water depleted gas mixture. The dual effect of water vapor on nickel-zirconia anode behaviour is discussed basing on scanning electron microscopy analysis data, material electrical conductivity, and strength.