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Preparation and Thermoelectric Characteristics of ITO/PtRh:PtRh Thin Film Thermocouple

机译:ITO / PtRh:PtRh薄膜热电偶的制备及热电特性

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摘要

Thin film thermocouples (TFTCs) can provide more precise in situ temperature measurement for aerospace propulsion systems without disturbance of gas flow and surface temperature distribution of the hot components. ITO>/PtRh:PtRh TFTC with multilayer structure was deposited on alumina ceramic substrate by magnetron sputtering. After annealing, the TFTC was statically calibrated for multiple cycles with temperature up to 1000 °C. The TFTC with excellent stability and repeatability was realized for the negligible variation of EMF in different calibration cycles. It is believed that owing to oxygen diffusion barriers by the oxidation of top PtRh layer and Schottky barriers formed at the grain boundaries of ITO, the variation of the carrier concentration of ITO film is minimized. Meanwhile, the life time of TFTC is more than 30 h in harsh environment. This makes ITO/PtRh:PtRh TFTC a promising candidate for precise surface temperature measurement of hot components of aeroengines.
机译:薄膜热电偶(TFTC)可以为航空航天推进系统提供更精确的原位温度测量,而不会干扰气体流动和热组件的表面温度分布。通过磁控溅射将具有多层结构的ITO > / PtRh:PtRh TFTC沉积在氧化铝陶瓷基板上。退火后,将TFTC静态校准了多个循环,温度高达1000°C。实现了具有优异稳定性和可重复性的TFTC,因为在不同的校准周期内EMF的变化可忽略不计。据信,由于顶部PtRh层的氧化产生的氧扩散势垒和在ITO的晶界处形成的肖特基势垒,使ITO膜的载流子浓度的变化最小。同时,在恶劣环境下TFTC的使用寿命超过30小时。这使得ITO / PtRh:PtRh TFTC成为航空发动机热部件精确表面温度测量的有希望的候选者。

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