首页> 美国卫生研究院文献>Nanoscale Research Letters >Humate-assisted Synthesis of MoS2/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries
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Humate-assisted Synthesis of MoS2/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries

机译:腐殖酸辅助共沉淀/煅烧合成高性能锂离子电池MoS2 / C纳米复合材料

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摘要

A facile, cost-effective, non-toxic, and surfactant-free route has been developed to synthesize MoS2/carbon (MoS2/C) nanocomposites. Potassium humate consists of a wide variety of oxygen-containing functional groups, which is considered as promising candidates for functionalization of graphene. Using potassium humate as carbon source, two-dimensional MoS2/C nanosheets with irregular shape were synthesized via a stabilized co-precipitation/calcination process. Electrochemical performance of the samples as an anode of lithium ion battery was measured, demonstrating that the MoS2/C nanocomposite calcinated at 700 °C (MoS2/C-700) electrode showed outstanding performance with a high discharge capacity of 554.9 mAh g− 1 at a current density of 100 mA g− 1 and the Coulomb efficiency of the sample maintained a high level of approximately 100% after the first 3 cycles. Simultaneously, the MoS2/C-700 electrode exhibited good cycling stability and rate performance. The success in synthesizing MoS2/C nanocomposites via co-precipitation/calcination route may pave a new way to realize promising anode materials for high-performance lithium ion batteries.Electronic supplementary materialThe online version of this article (10.1186/s11671-018-2537-y) contains supplementary material, which is available to authorized users.
机译:已经开发了一种简便,经济高效,无毒且不含表面活性剂的途径来合成MoS2 /碳(MoS2 / C)纳米复合材料。腐植酸钾由多种含氧官能团组成,被认为是石墨烯官能化的有前途的候选者。以腐植酸钾为碳源,通过稳定的共沉淀/煅烧工艺合成了不规则形状的二维MoS2 / C纳米片。测量了作为锂离子电池阳极的样品的电化学性能,表明在700°C(MoS2 / C-700)电极下煅烧的MoS2 / C纳米复合材料表现出出色的性能,其高放电容量为554.9 mAh g − 1 的电流密度为100mA g − 1 ,并且样品的库仑效率在前三个循环后保持约100%的高水平。同时,MoS2 / C-700电极表现出良好的循环稳定性和倍率性能。通过共沉淀/煅烧路线成功合成MoS2 / C纳米复合材料可能为实现高性能锂离子电池阳极材料铺平道路。电子补充材料本文的在线版本(10.1186 / s11671-018-2537- y)包含补充材料,授权用户可以使用。

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