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Electrospun Flexible Coaxial Nanoribbons Endowed With Tuned and Simultaneous Fluorescent Color-Electricity-Magnetism Trifunctionality

机译:具有静电调节功能的静电纺丝同轴纳米带同时具有荧光色-电-磁三功能

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摘要

In order to develop new-typed multifunctional nanocomposites, fluorescent-electrical-magnetic trifunctional coaxial nanoribbons with tunable fluorescent color, including white-light emission, have been successfully fabricated via coaxial electrospinning technology. Each stripe of coaxial nanoribbon is composed of a Fe3O4/PMMA core and a [Eu(BA)3phen+Dy(BA)3phen]/PANI/PMMA (PMMA = polymethyl methacrylate, BA = benzoic acid, phen = phenanthroline, polyaniline = PANI) shell. X-ray diffractometry (XRD), field emission scanning electron microscopy (FE-SEM), biological microscopy (BM), vibrating sample magnetometry (VSM), energy dispersive spectrometry (EDS), Hall effect measurement system and photoluminescence (PL) spectroscopy were employed to characterize the coaxial nanoribbons. Emitting color of the coaxial nanoribbons can be tuned by adjusting the contents of Dy(BA)3phen, Eu(BA)3phen, PANI and Fe3O4 in a wide color range of blue-white-orange under the excitation of 273-nm single-wavelength ultraviolet light. The coaxial nanoribbons simultaneously possess excellent luminescent performance, electrical conduction and magnetism compared with the counterpart composite nanoribbons. Furthermore, the electrical and magnetic performances of the coaxial nanoribbons also can be tunable by adding different quantities of PANI and Fe3O4 nanoparticles, respectively. The obtained coaxial nanoribbons have promising applications in many areas, such as electromagnetic interference shielding, microwave absorption, molecular electronics, biomedicine, future nanomechanics and display fields.
机译:为了开发新型的多功能纳米复合材料,已经通过同轴电纺技术成功地制备了具有可调荧光色,包括白光发射的荧光-电磁-电磁三功能同轴纳米带。每条同轴纳米带由Fe3O4 / PMMA核和[Eu(BA)3phen + Dy(BA)3phen] / PANI / PMMA(PMMA =聚甲基丙烯酸甲酯,BA =苯甲酸,phen =邻菲咯啉,聚苯胺= PANI组成) 贝壳。 X射线衍射法(XRD),场发射扫描电子显微镜(FE-SEM),生物显微镜(BM),振动样品磁力法(VSM),能量色散光谱法(EDS),霍尔效应测量系统和光致发光(PL)光谱用于表征同轴纳米带。可以通过在273nm单波长激发下在宽范围的蓝白橙色范围内调节Dy(BA)3phen,Eu(BA)3phen,PANI和Fe3O4的含量来调节同轴纳米带的发射颜色紫外光线。与相应的复合纳米带相比,同轴纳米带同时具有出色的发光性能,导电性和磁性。此外,通过分别添加不同量的PANI和Fe3O4纳米颗粒,同轴纳米带的电和磁性能也可以调节。所得的同轴纳米带在电磁干扰屏蔽,微波吸收,分子电子学,生物医学,未来的纳米力学和显示领域等许多领域具有广阔的应用前景。

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