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Limitation of Optical Enhancement in Ultra-thin Solar Cells Imposed by Contact Selectivity

机译:接触选择性对超薄太阳能电池光学增强的限制

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摘要

Ultra-thin crystalline silicon (c-Si) solar cell suffers both from poor light absorption and minority carrier recombination at the contacts resulting in low contact selectivity. Yet most of the research focuses on improving the light absorption by introducing novel light trapping technique. Our work shows that for ultra-thin absorber, the benefit of optical enhancement is limited by low contact selectivity. Using simulation we observe that performance enhancement from light trapping starts to saturate as the absorber scales down because of the increase in probability of the photo-generated carriers to recombine at the metal contact. Therefore, improving the carrier selectivity of the contacts, which reduces the recombination at contacts, is important to improve the performance of the solar cell beyond what is possible by enhancing light absorption only. The impact of improving contact selectivity increases as the absorber thickness scales below 20 micrometer (μm). Light trapping provides better light management and improving contact selectivity provides better photo-generated carrier management. When better light management increases the number of photo-generated carriers, better carrier management is a useful optimization knob to achieve the efficiency close to the thermodynamic limit. Our work explores a design trade-off in detail which is often overlooked by the research community.
机译:超薄晶体硅(c-Si)太阳能电池的光吸收率低,并且触点处的少数载流子复合,导致触点选择性低。然而,大多数研究集中在通过引入新颖的光捕获技术来改善光吸收。我们的工作表明,对于超薄吸收体,低接触选择性限制了光学增强的好处。通过仿真我们观察到,由于光生载流子在金属接触点重新结合的可能性增加,因此随着吸收剂的比例减小,光捕获带来的性能增强开始饱和。因此,改善接触件的载流子选择性(其减少了接触件处的复合)对于提高太阳能电池的性能至仅通过增强光吸收来实现的性能而言是重要的。当吸收器厚度缩小到20微米以下(μm)时,改善接触选择性的影响增加。捕光可提供更好的光管理,而改善的接触选择性可提供更好的光生载流子管理。当更好的光管理增加了光生载流子的数量时,更好的载流子管理是一种有用的优化旋钮,可实现接近热力学极限的效率。我们的工作详细探讨了设计折衷方案,而研究机构常常忽略了这种折衷方案。

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