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Low-frequency vibrational modes of stable glasses

机译:稳定眼镜的低频振动模式

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摘要

Unusual features of the vibrational density of states D(ω) of glasses allow one to rationalize their peculiar low-temperature properties. Simulational studies of D(ω) have been restricted to studying poorly annealed glasses that may not be relevant to experiments. Here we report on D(ω) of zero-temperature glasses with kinetic stabilities ranging from poorly annealed to ultrastable glasses. For all preparations, the low-frequency part of D(ω) splits between extended and quasi-localized modes. Extended modes exhibit a boson peak crossing over to Debye behavior (Dex(ω) ~ ω2) at low-frequency, with a strong correlation between the two regimes. Quasi-localized modes obey Dloc(ω) ~ ω4, irrespective of the stability. The prefactor of this quartic law decreases with increasing stability, and the corresponding modes become more localized and sparser. Our work is the first numerical observation of quasi-localized modes in a regime relevant to experiments, and it establishes a direct connection between glasses’ stability and their soft vibrational modes
机译:眼镜的状态振动密度D(ω)的不寻常特征使人们能够合理化其特殊的低温特性。 D(ω)的模拟研究仅限于研究与实验无关的退火不良的玻璃。在这里,我们报道了零温度玻璃的D(ω),其动力学稳定性从退火不良到超稳定玻璃不等。对于所有准备工作,D(ω)的低频部分在扩展模式和准局部模式之间分配。扩展模式在低频下表现出玻色子峰越过德拜行为(Dex(ω)〜ω 2 ),两者之间具有很强的相关性。拟局部化模式服从Dloc(ω)〜ω 4 ,而与稳定性无关。该四次律的前因因数随着稳定性的增加而减小,并且相应的模式变得更加局部化和稀疏。我们的工作是在与实验相关的状态下首次对准局域模进行数值观察,它建立了眼镜的稳定性和其柔和的振动模之间的直接联系。

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