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Feasibility of Detecting Bioorganic Compounds in Enceladus Plumes with the Enceladus Organic Analyzer

机译:用土卫二有机分析仪检测土卫二羽中生物有机物的可行性

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摘要

Enceladus presents an excellent opportunity to detect organic molecules that are relevant for habitability as well as bioorganic molecules that provide evidence for extraterrestrial life because Enceladus' plume is composed of material from the subsurface ocean that has a high habitability potential and significant organic content. A primary challenge is to send instruments to Enceladus that can efficiently sample organic molecules in the plume and analyze for the most relevant molecules with the necessary detection limits. To this end, we present the scientific feasibility and engineering design of the Enceladus Organic Analyzer (EOA) that uses a microfluidic capillary electrophoresis system to provide sensitive detection of a wide range of relevant organic molecules, including amines, amino acids, and carboxylic acids, with ppm plume-detection limits (100 pM limits of detection). Importantly, the design of a capture plate that effectively gathers plume ice particles at encounter velocities from 200 m/s to 5 km/s is described, and the ice particle impact is modeled to demonstrate that material will be efficiently captured without organic decomposition. While the EOA can also operate on a landed mission, the relative technical ease of a fly-by mission to Enceladus, the possibility to nondestructively capture pristine samples from deep within the Enceladus ocean, plus the high sensitivity of the EOA instrument for molecules of bioorganic relevance for life detection argue for the inclusion of EOA on Enceladus missions. Key Words: Lab-on-a-chip—Organic biomarkers—Life detection—Planetary exploration. Astrobiology 17, 902–912.
机译:土卫二提供了绝佳的机会来检测与宜居性相关的有机分子以及为外星生命提供证据的生物有机分子,因为土卫二的羽状羽绒是由来自地下海洋的物质组成,具有很高的宜居潜力并含有大量有机物。一个主要的挑战是将仪器发送到土卫二,以便可以有效地对羽流中的有机分子进行采样,并以必要的检测限分析最相关的分子。为此,我们介绍了土卫二有机分析仪(EOA)的科学可行性和工程设计,该分析仪使用微流体毛细管电泳系统对包括胺,氨基酸和羧酸在内的各种相关有机分子进行灵敏检测,具有ppm羽流检测极限(100 pM的检测极限)。重要的是,描述了一种捕获板的设计,该捕获板能以200 encounterm / s到5 km / s的遇到速度有效地收集羽状冰粒,并且对冰粒撞击进行建模以证明可以有效地捕获物质而不会发生有机分解。虽然EOA也可以执行登陆任务,但飞越Enceladus的技术相对容易,可以从Enceladus海洋深处无损捕获原始样品,而且EOA仪器对生物有机分子的高灵敏度与生命探测的相关性主张将EOA包含在Enceladus任务中。关键字:芯片实验室-有机生物标记物-生命探测-行星探测。天体生物学17,902–912。

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