{μ-NNN′N′-Tetra­kis(diphenyl­phosphan­yl)meth­ylbenzene-14-diamine}­bis­(22′-bipyrid­yl)copper(I) bis­(tetra­fluoridoborate)

摘要

In the title compound, [Cu2(C10H8N2)2(C58H52N2P4)](BF4)2, the dinuclear cation lies on an inversion centre. The Cu^I atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and two P atoms from an N,N,N′,N′-tetra­kis­[(diphenyl­phos­phan­yl)meth­yl]benzene-1,4-diamine ligand in a distorted tetra­hedral geometry. In the crystal, inter­molecular C—H⋯F hydrogen bonds link the ions into layers parallel to [01]. π–π inter­actions [centroid–centroid distance = 3.668 (4) Å] are also observed. One F atom of the anion is disordered over two orientations with a refined occupancy ratio of 0.675 (13):0.325 (13).