{μ-66′-Dimeth­oxy-22′-ethane-12-diyl­bis(nitrilo­methanylyl­idene)diphenolato-1κ4 O 6O 1O 1′O 6′;2κ4 O 1NN′O 1′}(methanol-1κO)(tetra­fluoridoborato-1κ2 FF′)-2-copper(II)-1-sodium

摘要

In the dinuclear salen-type title complex, [CuNa(BF4)(C18H18N2O4)(CH3OH)], the Cu^II atom is chelated by two O atoms and two N atoms of the deprotonated Schiff base in a square-planar geometry. The Na atom is seven-coordinate as it is linked to four O atoms of the same Schiff base ligand, one O atom of the methanol and two tetra­fluorido­borate F atoms. The remaining two F atoms of the anion are disordered over two sites in a 0.598 (18):0.402 (18) ratio.