(4E11E)-571214-Tetra­benzyl-714-dimethyl-14811-tetra­aza­cyclo­tetra­deca-411-dienecopper(II) bis(per­chlorate)

摘要

The complete cation in the title compound, [Cu(C40H48N4)](ClO4)2, is generated by the operation of a crystallographic centre of inversion. The Cu^II ion exists in a tetra­gonally distorted trans-N4O2 coordination geometry defined by the four N atoms of the macrocyclic ligand and two weakly bound perchlorate-O atoms from two anions. The N—H atoms form intra­molecular N—H⋯O(perchlorate) hydrogen bonds. Disorder was resolved in the –CH2–NH– portion of the macrocycle with the major component having a site-occupancy factor of 0.570 (6).