Polybis­μ-13-bis­(diphenyl­phosphan­yl)propane-κ2 P:P′-di-μ-thio­cyanato-κ2 S:N;κ2 N:S-disilver(I)

摘要

In the title coordination polymer, [Ag2(NCS)2(C27H26P2)2]n, two centrosymmetrically related Ag⁺ cations are linked by two thio­cyanate anions into binuclear eight-membered macrocycles. The Ag⋯Ag separation within the macrocycle is 5.4400 (6) Å. The distorted tetra­hedral coordination about each metal atom is completed by the P atoms of two bridging 1,3-bis­(diphenyl­phosphan­yl)propane ligands, forming polymeric ribbons parallel to the a axis.